Organic structural spectroscopyUpplaga 2

Chapter 1 Introduction 1-1    The Spectroscopic Approach to Structure Determination 1-2    Contributions of Different Forms of Spectroscopy 1-3    The Electromagnetic Spectrum 1-4    Molecular Weight and Molecular Formula 1-5    Structural Isomers and Stereoisomers Problems Part I  NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY Chapter 2 Introduction 2-1    Magnetic Properties of Nuclei 2-2    The Chemical Shift 2-3    Excitation and Relaxation 2-4    Pulsed Experiments 2-5    The Coupling Constant 2-6    Quantification and Complex Splitting 2-7    Commonly Studied Nuclides 2-8    Dynamic Effects 2-9    Spectra of Solids 2-10    Experimental Methods Problems Tips on Solving NMR Problems Bibliography Chapter 3 The Chemical Shift 3-1    Factors That Influence Proton Shifts 3-2    Proton Chemical Shifts and Structure 3-3    Medium and Isotope Effects 3-4    Factors That Influence Carbon Shirts 3-5    Carbon Chemical Shifts and Structure 3-6    Tables of Chemical Shifts Problems Further Tips on Solving NMR Problems Bibliography Chapter 4 The Coupling Constant 4-1    First-Order Spectra 4-2    Chemical and Magnetic Equivalence 4-3    Signs and Mechanisms 4-4    Couplings over One Bond 4-5    Geminal Couplings 4-6    Vicinal Couplings 4-7    Long-Range Couplings 4-8    Spectral Analysis 4-9    Second-Order Spectra 4-10    Tables of Coupling Constants Problems Bibliography Chapter 5 Further Topics in One-Dimensional NMR 5-1    Spin-Lattice and Spin-Spin Relaxation 5-2    Reactions on the NMR Time Scale 5-3    Multiple Resonance 5-4    The Nuclear Overhauser Effect 5-5    Spectral Editing 5-6    Sensitivity Enhancement 5-7    Carbon Connectivity 5-8    Phase Cycling, Composite Pulses, and Shaped Pulses Problems Bibliography Chapter 6 Two-Dimensional NMR 6-1    Proton-Proton Correlation Through Coupling 6-2    Proton-Heteronucleus Correlation 6-3    Proton-Proton Correlation Through Space or Chemical Exchange 6-4    Carbon-Carbon Correlation 6-5    Higher Dimensions 6-6    Pulsed Field Gradients 6-7    S...